LiBaAlF6 and the crystal chemistry of LiAIIBIIIF6 phases

Lithium barium hexafluoroaluminate (LBAF), LiBaAlF6, is a new member of the large family of compounds of formula LiAIIBIIIF6. These materials display a variety of structures depending on the sizes of the A and B cations. LiBaAlF6, which is isomorphous with LiBaCoF6, belongs to the monoclinic P21/c s...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2008-07, Vol.64 (7), p.i66-i68
Main Authors: Merkulov, Alexander A., Isaenko, Ludmila I., Lobanov, Sergey I., Naumov, Dmitry Yu, Kuratieva, Natalia V.
Format: Article
Language:English
Subjects:
Chemical compounds
Chemistry
Crystal structure
Crystallography
Lithium
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page i68
container_issue 7
container_start_page i66
container_title Acta crystallographica. Section C, Crystal structure communications
container_volume 64
creator Merkulov, Alexander A.
Isaenko, Ludmila I.
Lobanov, Sergey I.
Naumov, Dmitry Yu
Kuratieva, Natalia V.
description Lithium barium hexafluoroaluminate (LBAF), LiBaAlF6, is a new member of the large family of compounds of formula LiAIIBIIIF6. These materials display a variety of structures depending on the sizes of the A and B cations. LiBaAlF6, which is isomorphous with LiBaCoF6, belongs to the monoclinic P21/c subset and has a three‐dimensional network structure consisting of distorted LiF43− tetrahedra corner‐sharing with AlF63− octahedra and BaF12 polyhedra. All of the atoms reside on general positions. An analysis of the ionic radii of the A cations versus formula volumes for the known members of the family yields a structure map that reasonably segregates the compounds by space group. The data obtained are thus suitable for predicting new isomorphic crystal structures.
doi_str_mv 10.1107/S0108270108017538
format article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_69282637</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>69282637</sourcerecordid><originalsourceid>FETCH-LOGICAL-i1993-9a469d27e5e3c3fcc45c1805109a075f8ad75c2e31c3a72628d4ea5fef3b6af83</originalsourceid><addsrcrecordid>eNqFkU1PwkAQhjdGI4j-AC-m8eCturvT_ToCEWhsVILG6GWzbLehWD7sQpR_bxtQEz14mTm8zzuZeQehU4IvCcHiaoQJllTUFRPBQO6hJuEYh0wwtY-atRDWegMdeT_FGFNK4RA1iGRKKS6bSCZ5x7SLHg_MPA1WExfYcuNXpgjsxM1yvyo3wSILkrwdx504jitwOTHe-WN0kJnCu5Ndb6HH3vVDdxAmd_24207CnCgFoTIRVykVjjmwkFkbMUskZgQrgwXLpEkFs9QBsWAE5VSmkTMscxmMuckktNDFdu6yXLytnV_paivrisLM3WLtNVdUUg7iXxAiSiIOvALPf4HTxbqcV0doioGAYkxV0NkOWo9nLtXLMp-ZcqO_kqsAuQXe88JtfnSs69foP6_R7efuaAgkgsoabq1VvO7j22rKV80FCKafbvua3gyG7IXfawyfd4qLtQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>203139559</pqid></control><display><type>article</type><title>LiBaAlF6 and the crystal chemistry of LiAIIBIIIF6 phases</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><source>Alma/SFX Local Collection</source><creator>Merkulov, Alexander A. ; Isaenko, Ludmila I. ; Lobanov, Sergey I. ; Naumov, Dmitry Yu ; Kuratieva, Natalia V.</creator><creatorcontrib>Merkulov, Alexander A. ; Isaenko, Ludmila I. ; Lobanov, Sergey I. ; Naumov, Dmitry Yu ; Kuratieva, Natalia V.</creatorcontrib><description>Lithium barium hexafluoroaluminate (LBAF), LiBaAlF6, is a new member of the large family of compounds of formula LiAIIBIIIF6. These materials display a variety of structures depending on the sizes of the A and B cations. LiBaAlF6, which is isomorphous with LiBaCoF6, belongs to the monoclinic P21/c subset and has a three‐dimensional network structure consisting of distorted LiF43− tetrahedra corner‐sharing with AlF63− octahedra and BaF12 polyhedra. All of the atoms reside on general positions. An analysis of the ionic radii of the A cations versus formula volumes for the known members of the family yields a structure map that reasonably segregates the compounds by space group. The data obtained are thus suitable for predicting new isomorphic crystal structures.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270108017538</identifier><identifier>PMID: 18599968</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>Chemical compounds ; Chemistry ; Crystal structure ; Crystallography ; Lithium</subject><ispartof>Acta crystallographica. Section C, Crystal structure communications, 2008-07, Vol.64 (7), p.i66-i68</ispartof><rights>International Union of Crystallography, 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/18599968$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Merkulov, Alexander A.</creatorcontrib><creatorcontrib>Isaenko, Ludmila I.</creatorcontrib><creatorcontrib>Lobanov, Sergey I.</creatorcontrib><creatorcontrib>Naumov, Dmitry Yu</creatorcontrib><creatorcontrib>Kuratieva, Natalia V.</creatorcontrib><title>LiBaAlF6 and the crystal chemistry of LiAIIBIIIF6 phases</title><title>Acta crystallographica. Section C, Crystal structure communications</title><addtitle>Acta Cryst. C</addtitle><description>Lithium barium hexafluoroaluminate (LBAF), LiBaAlF6, is a new member of the large family of compounds of formula LiAIIBIIIF6. These materials display a variety of structures depending on the sizes of the A and B cations. LiBaAlF6, which is isomorphous with LiBaCoF6, belongs to the monoclinic P21/c subset and has a three‐dimensional network structure consisting of distorted LiF43− tetrahedra corner‐sharing with AlF63− octahedra and BaF12 polyhedra. All of the atoms reside on general positions. An analysis of the ionic radii of the A cations versus formula volumes for the known members of the family yields a structure map that reasonably segregates the compounds by space group. The data obtained are thus suitable for predicting new isomorphic crystal structures.</description><subject>Chemical compounds</subject><subject>Chemistry</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Lithium</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkU1PwkAQhjdGI4j-AC-m8eCturvT_ToCEWhsVILG6GWzbLehWD7sQpR_bxtQEz14mTm8zzuZeQehU4IvCcHiaoQJllTUFRPBQO6hJuEYh0wwtY-atRDWegMdeT_FGFNK4RA1iGRKKS6bSCZ5x7SLHg_MPA1WExfYcuNXpgjsxM1yvyo3wSILkrwdx504jitwOTHe-WN0kJnCu5Ndb6HH3vVDdxAmd_24207CnCgFoTIRVykVjjmwkFkbMUskZgQrgwXLpEkFs9QBsWAE5VSmkTMscxmMuckktNDFdu6yXLytnV_paivrisLM3WLtNVdUUg7iXxAiSiIOvALPf4HTxbqcV0doioGAYkxV0NkOWo9nLtXLMp-ZcqO_kqsAuQXe88JtfnSs69foP6_R7efuaAgkgsoabq1VvO7j22rKV80FCKafbvua3gyG7IXfawyfd4qLtQ</recordid><startdate>200807</startdate><enddate>200807</enddate><creator>Merkulov, Alexander A.</creator><creator>Isaenko, Ludmila I.</creator><creator>Lobanov, Sergey I.</creator><creator>Naumov, Dmitry Yu</creator><creator>Kuratieva, Natalia V.</creator><general>International Union of Crystallography</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>200807</creationdate><title>LiBaAlF6 and the crystal chemistry of LiAIIBIIIF6 phases</title><author>Merkulov, Alexander A. ; Isaenko, Ludmila I. ; Lobanov, Sergey I. ; Naumov, Dmitry Yu ; Kuratieva, Natalia V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i1993-9a469d27e5e3c3fcc45c1805109a075f8ad75c2e31c3a72628d4ea5fef3b6af83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemical compounds</topic><topic>Chemistry</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Lithium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Merkulov, Alexander A.</creatorcontrib><creatorcontrib>Isaenko, Ludmila I.</creatorcontrib><creatorcontrib>Lobanov, Sergey I.</creatorcontrib><creatorcontrib>Naumov, Dmitry Yu</creatorcontrib><creatorcontrib>Kuratieva, Natalia V.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Merkulov, Alexander A.</au><au>Isaenko, Ludmila I.</au><au>Lobanov, Sergey I.</au><au>Naumov, Dmitry Yu</au><au>Kuratieva, Natalia V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>LiBaAlF6 and the crystal chemistry of LiAIIBIIIF6 phases</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2008-07</date><risdate>2008</risdate><volume>64</volume><issue>7</issue><spage>i66</spage><epage>i68</epage><pages>i66-i68</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>Lithium barium hexafluoroaluminate (LBAF), LiBaAlF6, is a new member of the large family of compounds of formula LiAIIBIIIF6. These materials display a variety of structures depending on the sizes of the A and B cations. LiBaAlF6, which is isomorphous with LiBaCoF6, belongs to the monoclinic P21/c subset and has a three‐dimensional network structure consisting of distorted LiF43− tetrahedra corner‐sharing with AlF63− octahedra and BaF12 polyhedra. All of the atoms reside on general positions. An analysis of the ionic radii of the A cations versus formula volumes for the known members of the family yields a structure map that reasonably segregates the compounds by space group. The data obtained are thus suitable for predicting new isomorphic crystal structures.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><pmid>18599968</pmid><doi>10.1107/S0108270108017538</doi></addata></record>
fulltext fulltext
identifier ISSN: 0108-2701
ispartof Acta crystallographica. Section C, Crystal structure communications, 2008-07, Vol.64 (7), p.i66-i68
issn 0108-2701
1600-5759
language eng
recordid cdi_proquest_miscellaneous_69282637
source Wiley-Blackwell Read & Publish Collection; Alma/SFX Local Collection
subjects Chemical compounds
Chemistry
Crystal structure
Crystallography
Lithium
title LiBaAlF6 and the crystal chemistry of LiAIIBIIIF6 phases
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T09%3A24%3A19IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=LiBaAlF6%20and%20the%20crystal%20chemistry%20of%20LiAIIBIIIF6%20phases&rft.jtitle=Acta%20crystallographica.%20Section%20C,%20Crystal%20structure%20communications&rft.au=Merkulov,%20Alexander%20A.&rft.date=2008-07&rft.volume=64&rft.issue=7&rft.spage=i66&rft.epage=i68&rft.pages=i66-i68&rft.issn=0108-2701&rft.eissn=1600-5759&rft_id=info:doi/10.1107/S0108270108017538&rft_dat=%3Cproquest_pubme%3E69282637%3C/proquest_pubme%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-i1993-9a469d27e5e3c3fcc45c1805109a075f8ad75c2e31c3a72628d4ea5fef3b6af83%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=203139559&rft_id=info:pmid/18599968&rfr_iscdi=true