High Uptakes of CO2 and CH4 in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101

Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO2 and CH4. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gassolid interactions. In particular, the uptake of carbon dioxide...

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Bibliographic Details
Published in:Langmuir 2008-07, Vol.24 (14), p.7245-7250
Main Authors: Llewellyn, Philip L, Bourrelly, Sandrine, Serre, Christian, Vimont, Alexandre, Daturi, Marco, Hamon, Lomig, De Weireld, Guy, Chang, Jong-San, Hong, Do-Young, Kyu Hwang, Young, Hwa Jhung, Sung, Férey, Gérard
Format: Article
Language:English
Subjects:
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Interfaces: Adsorption, Reactions, Films, Forces
Porous materials
Surface physical chemistry
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Summary:Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO2 and CH4. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gassolid interactions. In particular, the uptake of carbon dioxide in MIL-101 has been shown to occur with a record capacity of 40 mmol g−1 or 390 cm3 STP cm−3 at 5 MPa and 303 K.
ISSN:0743-7463
1520-5827
DOI:10.1021/la800227x