Raman spectra of complexes of HNO3 and NO3- with NO2 at surfaces and with N2O4 in solution

Raman spectra of HNO(3).NO(2) have been detected on liquid and solid surfaces in the presence of concentrated HNO(3) and NO(2) gas. The Raman spectrum of HNO(3) solutions containing N(2)O(4) has been partly reinterpreted in terms of contributions from HNO(3).N(2)O(4) and N(2)O(4).NO(3)(-) complexes.

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2008-08, Vol.10 (32), p.4748-4753
Main Authors: Kamboures, Michael A, van der Veer, Wytze, Gerber, R Benny, Phillips, Leon F
Format: Article
Language:English
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Summary:Raman spectra of HNO(3).NO(2) have been detected on liquid and solid surfaces in the presence of concentrated HNO(3) and NO(2) gas. The Raman spectrum of HNO(3) solutions containing N(2)O(4) has been partly reinterpreted in terms of contributions from HNO(3).N(2)O(4) and N(2)O(4).NO(3)(-) complexes.
ISSN:1463-9076
1463-9084
DOI:10.1039/b810081k