Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra

Metal−organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M2(CO2)4 (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and cr...

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Published in:Journal of the American Chemical Society 2008-09, Vol.130 (35), p.11650-11661
Main Authors: Furukawa, Hiroyasu, Kim, Jaheon, Ockwig, Nathan W, O’Keeffe, Michael, Yaghi, Omar M
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Language:English
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cited_by cdi_FETCH-LOGICAL-a417t-36d00e4c1b61aaf1fb33daa86f2baf55b69d3f6d75482e70fe0f31c2951cb54b3
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container_end_page 11661
container_issue 35
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container_title Journal of the American Chemical Society
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creator Furukawa, Hiroyasu
Kim, Jaheon
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O’Keeffe, Michael
Yaghi, Omar M
description Metal−organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M2(CO2)4 (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and crystal structures of 5 new MOPs and 11 new MOFs (termed MOP-14, -15, -17, -23, -24 and MOF-114, -115, -116, -117, -118, -119, -222, -601, -602, -603, -604) and show how their structures are related to the shape and functionality of the building blocks. The gas uptake behaviors of MOP-23 and MOF-601 to -603 are also presented as evidence that these structures have permanent porosity and rigid architectures.
doi_str_mv 10.1021/ja803783c
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title Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra
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