Highly Diastereoselective and Enantioselective Formal [4 + 1] Ylide Annulation for the Synthesis of Optically Active Dihydrofurans

On the basis of the reactions of camphor-derived sulfur ylide with α-ylidene-β-diketones, highly efficient and selective synthesis of optically active dihydrofurans has been achieved.

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Bibliographic Details
Published in:Journal of organic chemistry 2008-09, Vol.73 (17), p.6909-6912
Main Authors: Zheng, Jun-Cheng, Zhu, Chun-Yin, Sun, Xiu-Li, Tang, Yong, Dai, Li-Xin
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Organic chemistry
Preparations and properties
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Description
Summary:On the basis of the reactions of camphor-derived sulfur ylide with α-ylidene-β-diketones, highly efficient and selective synthesis of optically active dihydrofurans has been achieved.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo801135j