Theory and simulation in heterogeneous gold catalysis

This critical review covers the application of quantum chemistry to the burgeoning area of the heterogeneous oxidation by Au. We focus on the most established reaction, the oxidation of CO at low temperature. The review begins with an overview of the methods available comparing the treatment of the...

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Bibliographic Details
Published in:Chemical Society reviews 2008-09, Vol.37 (9), p.2046-2076
Main Authors: Coquet, Rudy, Howard, Kara L, Willock, David J
Format: Article
Language:English
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Summary:This critical review covers the application of quantum chemistry to the burgeoning area of the heterogeneous oxidation by Au. We focus on the most established reaction, the oxidation of CO at low temperature. The review begins with an overview of the methods available comparing the treatment of the electron-electron interaction and relativistic effects. The structure of Au particles and their interaction with oxide reviews is then discussed in detail. Calculations of the adsorption and reaction of CO and O2 are then considered and results from isolated and supported Au clusters compared (155 references).
ISSN:0306-0012
1460-4744
DOI:10.1039/b707385m