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Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts
In the present study, such carbohydrate-derived catalysts have been prepared from various carbohydrates such as d-glucose, sucrose, cellulose and starch. The catalytic and textural properties of the prepared catalysts have been investigated in detail and it was found that the starch-derived catalyst...
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| Published in: | Bioresource technology 2008-12, Vol.99 (18), p.8752-8758 |
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| cited_by | cdi_FETCH-LOGICAL-c482t-22ce24c42b18f75ef58de89041ff8cd88859bb9022c728879585fbb3087347e43 |
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| cites | cdi_FETCH-LOGICAL-c482t-22ce24c42b18f75ef58de89041ff8cd88859bb9022c728879585fbb3087347e43 |
| container_end_page | 8758 |
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| container_title | Bioresource technology |
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| creator | Lou, Wen-Yong Zong, Min-Hua Duan, Zhang-Qun |
| description | In the present study, such carbohydrate-derived catalysts have been prepared from various carbohydrates such as
d-glucose, sucrose, cellulose and starch. The catalytic and textural properties of the prepared catalysts have been investigated in detail and it was found that the starch-derived catalyst had the best catalytic performance. The carbohydrate-derived catalysts exhibited substantially higher catalytic activities for both esterification and transesterification compared to the two typical solid acid catalysts (sulphated zirconia and Niobic acid), and gave markedly enhanced yield of methyl esters in converting waste cooking oils containing 27.8
wt% high free fatty acids (FFAs) to biodiesel. In addition, under the optimized reaction conditions, the starch-derived catalyst retained a remarkably high proportion (about 93%) of its original catalytic activity even after 50 cycles of successive re-use and thus displayed very excellent operational stability. Our results clearly indicate that the carbohydrate-derived catalysts, especially the starch-derived catalyst, are highly effective, recyclable, eco-friendly and promising solid acid catalysts that are highly suited to the production of biodiesel from waste oils containing high FFAs. |
| doi_str_mv | 10.1016/j.biortech.2008.04.038 |
| format | article |
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d-glucose, sucrose, cellulose and starch. The catalytic and textural properties of the prepared catalysts have been investigated in detail and it was found that the starch-derived catalyst had the best catalytic performance. The carbohydrate-derived catalysts exhibited substantially higher catalytic activities for both esterification and transesterification compared to the two typical solid acid catalysts (sulphated zirconia and Niobic acid), and gave markedly enhanced yield of methyl esters in converting waste cooking oils containing 27.8
wt% high free fatty acids (FFAs) to biodiesel. In addition, under the optimized reaction conditions, the starch-derived catalyst retained a remarkably high proportion (about 93%) of its original catalytic activity even after 50 cycles of successive re-use and thus displayed very excellent operational stability. Our results clearly indicate that the carbohydrate-derived catalysts, especially the starch-derived catalyst, are highly effective, recyclable, eco-friendly and promising solid acid catalysts that are highly suited to the production of biodiesel from waste oils containing high FFAs.</description><identifier>ISSN: 0960-8524</identifier><identifier>EISSN: 1873-2976</identifier><identifier>DOI: 10.1016/j.biortech.2008.04.038</identifier><identifier>PMID: 18504123</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Acids ; Applied sciences ; biodiesel ; Biodiesel production ; Bioelectric Energy Sources ; Biofuel production ; Biological and medical sciences ; Biotechnology ; Carbohydrate-derived catalysts ; Carbohydrates - chemistry ; Catalysis ; catalysts ; cellulose ; cooking fats and oils ; Energy ; Esterification ; Exact sciences and technology ; Fatty Acids, Nonesterified - metabolism ; food wastes ; free fatty acids ; Fundamental and applied biological sciences. Psychology ; glucose ; High FFAs ; Industrial applications and implications. Economical aspects ; methyl esters ; Plant Oils - metabolism ; Pollution ; Refuse Disposal ; Spectrum Analysis ; starch ; Starch-derived solid acid catalyst ; sucrose ; texture ; Time Factors ; transesterification ; Waste oils ; waste utilization ; Wastes ; yields</subject><ispartof>Bioresource technology, 2008-12, Vol.99 (18), p.8752-8758</ispartof><rights>2008 Elsevier Ltd</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c482t-22ce24c42b18f75ef58de89041ff8cd88859bb9022c728879585fbb3087347e43</citedby><cites>FETCH-LOGICAL-c482t-22ce24c42b18f75ef58de89041ff8cd88859bb9022c728879585fbb3087347e43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20790665$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/18504123$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lou, Wen-Yong</creatorcontrib><creatorcontrib>Zong, Min-Hua</creatorcontrib><creatorcontrib>Duan, Zhang-Qun</creatorcontrib><title>Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts</title><title>Bioresource technology</title><addtitle>Bioresour Technol</addtitle><description>In the present study, such carbohydrate-derived catalysts have been prepared from various carbohydrates such as
d-glucose, sucrose, cellulose and starch. The catalytic and textural properties of the prepared catalysts have been investigated in detail and it was found that the starch-derived catalyst had the best catalytic performance. The carbohydrate-derived catalysts exhibited substantially higher catalytic activities for both esterification and transesterification compared to the two typical solid acid catalysts (sulphated zirconia and Niobic acid), and gave markedly enhanced yield of methyl esters in converting waste cooking oils containing 27.8
wt% high free fatty acids (FFAs) to biodiesel. In addition, under the optimized reaction conditions, the starch-derived catalyst retained a remarkably high proportion (about 93%) of its original catalytic activity even after 50 cycles of successive re-use and thus displayed very excellent operational stability. Our results clearly indicate that the carbohydrate-derived catalysts, especially the starch-derived catalyst, are highly effective, recyclable, eco-friendly and promising solid acid catalysts that are highly suited to the production of biodiesel from waste oils containing high FFAs.</description><subject>Acids</subject><subject>Applied sciences</subject><subject>biodiesel</subject><subject>Biodiesel production</subject><subject>Bioelectric Energy Sources</subject><subject>Biofuel production</subject><subject>Biological and medical sciences</subject><subject>Biotechnology</subject><subject>Carbohydrate-derived catalysts</subject><subject>Carbohydrates - chemistry</subject><subject>Catalysis</subject><subject>catalysts</subject><subject>cellulose</subject><subject>cooking fats and oils</subject><subject>Energy</subject><subject>Esterification</subject><subject>Exact sciences and technology</subject><subject>Fatty Acids, Nonesterified - metabolism</subject><subject>food wastes</subject><subject>free fatty acids</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>glucose</subject><subject>High FFAs</subject><subject>Industrial applications and implications. Economical aspects</subject><subject>methyl esters</subject><subject>Plant Oils - metabolism</subject><subject>Pollution</subject><subject>Refuse Disposal</subject><subject>Spectrum Analysis</subject><subject>starch</subject><subject>Starch-derived solid acid catalyst</subject><subject>sucrose</subject><subject>texture</subject><subject>Time Factors</subject><subject>transesterification</subject><subject>Waste oils</subject><subject>waste utilization</subject><subject>Wastes</subject><subject>yields</subject><issn>0960-8524</issn><issn>1873-2976</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFks2OFCEUhStG47SjrzCy0V21FwqqqJ1mMv4kk7jQWRMKLt10qosRqDb9CL61lN3qslcQ-O6553KoqhsKawq0fbdbDz7EjGa7ZgByDXwNjXxSrajsmpr1Xfu0WkHfQi0F41fVi5R2ANDQjj2vrqgUwClrVtWvO-e88Thl8hiDnU32YSLBkSJvPSYciYthT7Z-sy07ROJ0zkeijbe1CVPWfvLThvzUKSMJfkxkTsvBQUcf5kSMjkPYHm3UGWuL0R_QkhRGb_9olPusx2PK6WX1zOkx4avzel09fLz7fvu5vv_66cvth_vacMlyzZhBxg1nA5WuE-iEtCj7Mo5z0lgppeiHoYfCdUzKrhdSuGFooLwL75A319Xbk26Z98eMKau9TwbHUU9YDKu2FwAtg4sgW4IQvL8IUl5s8HZRbE-giSGliE49Rr_X8agoqEVN7dTfWNUSqwKuSqyl8ObcYR72aP-XnXMswJszoJPRo4t6Mj794xh0PbStKNzrE-d0UHoTC_PwjQFtgIpGUEoL8f5EYMng4DGqtHwPg9ZHNFnZ4C-5_Q2MU888</recordid><startdate>20081201</startdate><enddate>20081201</enddate><creator>Lou, Wen-Yong</creator><creator>Zong, Min-Hua</creator><creator>Duan, Zhang-Qun</creator><general>Elsevier Ltd</general><general>[New York, NY]: Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>20081201</creationdate><title>Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts</title><author>Lou, Wen-Yong ; Zong, Min-Hua ; Duan, Zhang-Qun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c482t-22ce24c42b18f75ef58de89041ff8cd88859bb9022c728879585fbb3087347e43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Acids</topic><topic>Applied sciences</topic><topic>biodiesel</topic><topic>Biodiesel production</topic><topic>Bioelectric Energy Sources</topic><topic>Biofuel production</topic><topic>Biological and medical sciences</topic><topic>Biotechnology</topic><topic>Carbohydrate-derived catalysts</topic><topic>Carbohydrates - chemistry</topic><topic>Catalysis</topic><topic>catalysts</topic><topic>cellulose</topic><topic>cooking fats and oils</topic><topic>Energy</topic><topic>Esterification</topic><topic>Exact sciences and technology</topic><topic>Fatty Acids, Nonesterified - metabolism</topic><topic>food wastes</topic><topic>free fatty acids</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>glucose</topic><topic>High FFAs</topic><topic>Industrial applications and implications. Economical aspects</topic><topic>methyl esters</topic><topic>Plant Oils - metabolism</topic><topic>Pollution</topic><topic>Refuse Disposal</topic><topic>Spectrum Analysis</topic><topic>starch</topic><topic>Starch-derived solid acid catalyst</topic><topic>sucrose</topic><topic>texture</topic><topic>Time Factors</topic><topic>transesterification</topic><topic>Waste oils</topic><topic>waste utilization</topic><topic>Wastes</topic><topic>yields</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lou, Wen-Yong</creatorcontrib><creatorcontrib>Zong, Min-Hua</creatorcontrib><creatorcontrib>Duan, Zhang-Qun</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Bioresource technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lou, Wen-Yong</au><au>Zong, Min-Hua</au><au>Duan, Zhang-Qun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts</atitle><jtitle>Bioresource technology</jtitle><addtitle>Bioresour Technol</addtitle><date>2008-12-01</date><risdate>2008</risdate><volume>99</volume><issue>18</issue><spage>8752</spage><epage>8758</epage><pages>8752-8758</pages><issn>0960-8524</issn><eissn>1873-2976</eissn><abstract>In the present study, such carbohydrate-derived catalysts have been prepared from various carbohydrates such as
d-glucose, sucrose, cellulose and starch. The catalytic and textural properties of the prepared catalysts have been investigated in detail and it was found that the starch-derived catalyst had the best catalytic performance. The carbohydrate-derived catalysts exhibited substantially higher catalytic activities for both esterification and transesterification compared to the two typical solid acid catalysts (sulphated zirconia and Niobic acid), and gave markedly enhanced yield of methyl esters in converting waste cooking oils containing 27.8
wt% high free fatty acids (FFAs) to biodiesel. In addition, under the optimized reaction conditions, the starch-derived catalyst retained a remarkably high proportion (about 93%) of its original catalytic activity even after 50 cycles of successive re-use and thus displayed very excellent operational stability. Our results clearly indicate that the carbohydrate-derived catalysts, especially the starch-derived catalyst, are highly effective, recyclable, eco-friendly and promising solid acid catalysts that are highly suited to the production of biodiesel from waste oils containing high FFAs.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>18504123</pmid><doi>10.1016/j.biortech.2008.04.038</doi><tpages>7</tpages></addata></record> |
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| ispartof | Bioresource technology, 2008-12, Vol.99 (18), p.8752-8758 |
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| source | ScienceDirect Freedom Collection |
| subjects | Acids Applied sciences biodiesel Biodiesel production Bioelectric Energy Sources Biofuel production Biological and medical sciences Biotechnology Carbohydrate-derived catalysts Carbohydrates - chemistry Catalysis catalysts cellulose cooking fats and oils Energy Esterification Exact sciences and technology Fatty Acids, Nonesterified - metabolism food wastes free fatty acids Fundamental and applied biological sciences. Psychology glucose High FFAs Industrial applications and implications. Economical aspects methyl esters Plant Oils - metabolism Pollution Refuse Disposal Spectrum Analysis starch Starch-derived solid acid catalyst sucrose texture Time Factors transesterification Waste oils waste utilization Wastes yields |
| title | Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts |
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