Cluster emission and chemical reactions in oxygen and nitrogen ices induced by fast heavy-ion impact

• Published in: Journal of mass spectrometry. 2008-11, Vol.43 (11), p.1521-1530
• Main Authors: Ponciano, C.R, Martinez, R, Farenzena, L.S, Iza, P, Homem, M.G.P, Naves de Brito, A, Wien, K, da Silveira, E.F
• Format: Article
• Language: English
• Subjects: Chemistry; cluster ions; condensed gases; Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...); Exact sciences and technology; Inorganic chemistry and origins of life; O2 ice; O2-N2 ice; Preparations and properties; secondary ions; temperature dependence; TOF-SIMS
• ISSN: 1076-5174; 1096-9888
• DOI: 10.1002/jms.1429

Two ices, O₂ and a mixture of O₂ and N₂, are bombarded by ²⁵²Cf fission fragments (FF) (~65 MeV at target surface); the emitted positive and negative secondary ions are analyzed by time-of-flight mass spectrometry (TOF-SIMS). These studies shall enlighten sputtering from planetary and interstellar ices. Three temperature regions in the 28-42-K range are analyzed: (1) before N₂ sublimation, in which hybrid chemical species are formed, (2) before O₂ sublimation, in which the TOF mass spectrum is dominated by low-mass (O₂)p cluster ions and (3) after O₂ sublimation, in which (N₂)p or (O₂)p cluster ions are practically inexistent. In the first region, four hybrid ion series are observed: NOn₋₁ ⁺, N₂On₋₂ ±, and N₄On₋₄ ⁻. In the second region, two positive and negative ion series are identified: (O₂)pO± and (O₂)pO₂ ±. Their yield distributions are fitted by the sum of two decreasing exponentials, whose decay constants are the same for all series. It is observed that the cluster ion desorption from solid oxygen is very similar to that of other frozen gases, but its yield distribution oscillates with a three- or six-atom periodicity, suggesting O₃ or 3O₂ units in the cluster structure, respectively. Copyright © 2008 John Wiley & Sons, Ltd.