Template-Directed Assembly of Zeolite-like Metal-Organic Frameworks (ZMOFs): A usf-ZMOF with an Unprecedented Zeolite Topology

Better off med: The assembly of eight‐coordinate indium molecular building blocks (MBBs) and 4,5‐imidazoledicarboxylate (Himdc) ligands in the presence of a structure‐directing agent results in the formation a novel 4‐connected zeolite‐like metal–organic framework (ZMOF) with an unprecedented zeolit...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2008-01, Vol.47 (44), p.8446-8449
Main Authors: Liu, Yunling, Kravtsov, Victor Ch, Eddaoudi, Mohamed
Format: Article
Language:English
Subjects:
indium
metal–organic frameworks
porous materials
template synthesis
zeolite analogues
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Summary:Better off med: The assembly of eight‐coordinate indium molecular building blocks (MBBs) and 4,5‐imidazoledicarboxylate (Himdc) ligands in the presence of a structure‐directing agent results in the formation a novel 4‐connected zeolite‐like metal–organic framework (ZMOF) with an unprecedented zeolite topology (med topology, see picture; In green, C gray, N blue, O red; the framework topology of usf‐ZMOF is shown in green tetrahedra).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200802680