Heterogeneous Catalysis through Microcontact Printing

Minting a Stamp: The preparation of copper metal‐coated elastomeric stamps and their use in catalyzing the Cu‐catalyzed azide–alkyne cycloaddition reaction heterogeneously through microcontact printing is described (see scheme). This StampCat process is compared to other conventional surface‐functio...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2008-01, Vol.47 (51), p.9927-9932
Main Authors: Spruell, Jason M, Sheriff, Bonnie A, Rozkiewicz, Dorota I, Dichtel, William R, Rohde, Rosemary D, Reinhoudt, David N, Stoddart, J. Fraser, Heath, James R
Format: Article
Language:English
Subjects:
azide–alkyne cycloaddition
heterogeneous catalysis
microcontact printing
StampCat
surface chemistry
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Summary:Minting a Stamp: The preparation of copper metal‐coated elastomeric stamps and their use in catalyzing the Cu‐catalyzed azide–alkyne cycloaddition reaction heterogeneously through microcontact printing is described (see scheme). This StampCat process is compared to other conventional surface‐functionalization techniques, including traditional microcontact printing and solution–surface‐based reactions.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200803480