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Synthesis and catalytic performance of Ti-MCM-68 for effective oxidation reactions

Microporous titanosilicate Ti-MCM-68 (Ti-MSE) was successfully synthesized by post-synthetic isomorphous substitution of Ti for Al and proved to be a high-performance catalyst, in particular showing superior performance to TS-1, Ti-BEA, and Ti-MWW for phenol oxidation using H(2)O(2) as an oxidant.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2008-01 (46), p.6224-6226
Main Authors: Kubota, Yoshihiro, Koyama, Yoshihito, Yamada, Taku, Inagaki, Satoshi, Tatsumi, Takashi
Format: Article
Language:English
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Summary:Microporous titanosilicate Ti-MCM-68 (Ti-MSE) was successfully synthesized by post-synthetic isomorphous substitution of Ti for Al and proved to be a high-performance catalyst, in particular showing superior performance to TS-1, Ti-BEA, and Ti-MWW for phenol oxidation using H(2)O(2) as an oxidant.
ISSN:1359-7345
1364-548X
DOI:10.1039/b814286f