Monolayer properties of surface-active metalorganic complexes with a tunable headgroup

Surface-active metalorganic complexes can be used to construct organic thin films with excellent electronic and catalytic properties. We have recently introduced a new versatile surface-active ligand, which can efficiently coordinate a wide range of transition metals. In the present work we report a...

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Published in:Journal of colloid and interface science 2008-01, Vol.317 (2), p.544-555
Main Authors: Mallouri, R., Keramidas, A.D., Brezesinski, G., Leontidis, E.
Format: Article
Language:English
Subjects:
Brewster angle microscopy
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
GIXD
Langmuir blodgett films
Langmuir monolayer
Langmuir–Blodgett film
Metalorganic complex
Surface physical chemistry
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container_title Journal of colloid and interface science
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creator Mallouri, R.
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description Surface-active metalorganic complexes can be used to construct organic thin films with excellent electronic and catalytic properties. We have recently introduced a new versatile surface-active ligand, which can efficiently coordinate a wide range of transition metals. In the present work we report an investigation of Langmuir monolayers of V V, Mo VI and Ti IV complexes of this ligand, using surface pressure–area isotherms, Brewster-angle microscopy, and Grazing incidence X-ray diffraction. The monolayers of these complexes are stable enough over broad temperature ranges to allow efficient transfer to solid substrates.
doi_str_mv 10.1016/j.jcis.2007.09.058
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subjects Brewster angle microscopy
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
GIXD
Langmuir blodgett films
Langmuir monolayer
Langmuir–Blodgett film
Metalorganic complex
Surface physical chemistry
title Monolayer properties of surface-active metalorganic complexes with a tunable headgroup
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