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Weak Correlations between Local Density and Dynamics near the Glass Transition
We perform experiments on two different dense colloidal suspensions with confocal microscopy to probe the relationship between local structure and dynamics near the glass transition. We calculate the Voronoi volume for our particles and show that this quantity is not a universal probe of glassy stru...
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| Published in: | The journal of physical chemistry. B 2005-11, Vol.109 (45), p.21235-21240 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-a417t-13f5c711a400ae4d98942ec0279d0cbccf167589d15557cc0f91acb2dc210f553 |
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| cites | cdi_FETCH-LOGICAL-a417t-13f5c711a400ae4d98942ec0279d0cbccf167589d15557cc0f91acb2dc210f553 |
| container_end_page | 21240 |
| container_issue | 45 |
| container_start_page | 21235 |
| container_title | The journal of physical chemistry. B |
| container_volume | 109 |
| creator | Conrad, J. C. Starr, F. W. Weitz, D. A. |
| description | We perform experiments on two different dense colloidal suspensions with confocal microscopy to probe the relationship between local structure and dynamics near the glass transition. We calculate the Voronoi volume for our particles and show that this quantity is not a universal probe of glassy structure for all colloidal suspensions. We correlate the Voronoi volume to displacement and find that these quantities are only weakly correlated. We observe qualitatively similar results in a simulation of a polymer melt. These results suggest that the Voronoi volume does not predict dynamical behavior in experimental colloidal suspensions; a purely structural approach based on local single particle volume likely cannot describe the colloidal glass transition. |
| doi_str_mv | 10.1021/jp0514168 |
| format | article |
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| ispartof | The journal of physical chemistry. B, 2005-11, Vol.109 (45), p.21235-21240 |
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| source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
| title | Weak Correlations between Local Density and Dynamics near the Glass Transition |
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