Thermal decomposition of struvite and its phase transition

• Published in: Chemosphere (Oxford) 2008-02, Vol.70 (8), p.1347-1356
• Main Authors: Bhuiyan, M. Iqbal H., Mavinic, D.S., Koch, F.A.
• Format: Article
• Language: English
• Subjects: Applied sciences; Bobierrite; Crystallization; Dittmarite; Exact sciences and technology; Fluidized bed reactor; General purification processes; Magnesium Compounds - chemistry; Phase Transition; Phosphates - chemistry; Pollution; Struvite; Temperature; Waste Disposal, Fluid - instrumentation; Waste Disposal, Fluid - methods; Wastewater; Wastewaters; Water Purification - instrumentation; Water Purification - methods; Water treatment and pollution
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2007.09.056

Intentional crystallization of struvite, before it forms and accumulates on wastewater treatment equipment, solves an important and costly wastewater treatment problem and on the other hand, provides an environmentally sound and renewable nutrient source to the agricultural industry. Struvite was synthesized in the laboratory; it was also produced as pellets in a pilot-scale, fluidized bed reactor, using real centrate resulting from an anaerobic digester. The thermal decomposition of both synthetic struvite and struvite pellets was studied. The decomposition of struvite was found to be dependent on the rate of heating. Through gradual loss of ammonia and water molecules, ultimately struvite was found to be transformed into amorphous magnesium hydrogen phosphate. When struvite was heated in excess water, it was partially transformed into bobierrite, through the gradual loss of ammonia. It was transformed into monohydrate, dittmarite by losing its five water molecules of crystallization, when boiled in excess water.