Photochemical [2 + 2] cycloaddition as a tool to study a solid-state structural transformation

The solid-state structural transformation of the hydrogen-bonded 1D coordination polymer [Cd(bpe)(CH(3)COO)(2)(H(2)O)](n), to a ladder-type structure is evident from a photochemical [2 + 2] cycloaddition reaction forming 100% rctt-cyclobutane isomer.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2008-01 (4), p.438-440
Main Authors: Nagarathinam, Mangayarkarasi, Vittal, Jagadese J
Format: Article
Language:English
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Summary:The solid-state structural transformation of the hydrogen-bonded 1D coordination polymer [Cd(bpe)(CH(3)COO)(2)(H(2)O)](n), to a ladder-type structure is evident from a photochemical [2 + 2] cycloaddition reaction forming 100% rctt-cyclobutane isomer.
ISSN:1359-7345
1364-548X
DOI:10.1039/b713586f