Li₆PS₅X: A Class of Crystalline Li-Rich Solids With an Unusually High Li⁺ Mobility

Mobile metal ions: Halide‐substituted lithium argyrodites form a new class of Li‐rich solids with an unusually high Li mobility. Single‐crystal X‐ray studies (see picture; Li black, S yellow, I red) at room temperature and MAS‐NMR measurements in a wide temperature range provide insights into the Li...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2008-01, Vol.47 (4), p.755-758
Main Authors: Deiseroth, Hans-Jörg, Kong, Shiao-Tong, Eckert, Hellmut, Vannahme, Julia, Reiner, Christof, Zaiß, Torsten, Schlosser, Marc
Format: Article
Language:English
Subjects:
argyrodites
conducting materials
halides
lithium
NMR spectroscopy
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Summary:Mobile metal ions: Halide‐substituted lithium argyrodites form a new class of Li‐rich solids with an unusually high Li mobility. Single‐crystal X‐ray studies (see picture; Li black, S yellow, I red) at room temperature and MAS‐NMR measurements in a wide temperature range provide insights into the Li+ ion dynamics.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200703900