A Record Anisotropy Barrier for a Single-Molecule Magnet

Structural distortion in a [Mn6] complex switches the magnetic exchange from antiferro- to ferromagnetic, resulting in a single-molecule magnet with a record anisotropy barrier.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2007-03, Vol.129 (10), p.2754-2755
Main Authors: Milios, Constantinos J, Vinslava, Alina, Wernsdorfer, Wolfgang, Moggach, Stephen, Parsons, Simon, Perlepes, Spyros P, Christou, George, Brechin, Euan K
Format: Article
Language:English
Subjects:
Anisotropy
Magnetics
Manganese - chemistry
Molecular Structure
Organometallic Compounds - chemistry
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Description
Summary:Structural distortion in a [Mn6] complex switches the magnetic exchange from antiferro- to ferromagnetic, resulting in a single-molecule magnet with a record anisotropy barrier.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja068961m