Cu-Catalyzed Synthesis of Symmetric Group 6 (Fischer) Bis-carbene Complexes

The efficient copper oxidative homocoupling (CuCl/TMEDA/O2) of alkynyl Fischer carbene complexes yields bis-carbene complexes having π-tethers. The bimetallic complexes are exceptional templates to prepare diverse organic symmetric structures connected by π-extended fragments.

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Published in:Organic letters 2008-02, Vol.10 (3), p.365-368
Main Authors: López-Alberca, María P, Mancheño, María J, Fernández, Israel, Gómez-Gallego, Mar, Sierra, Miguel A
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Language:English
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cited_by cdi_FETCH-LOGICAL-a313t-86087eacc2f9c0109c88ca339b7b9841fff19e6396d806d16f33cec43bb222af3
cites cdi_FETCH-LOGICAL-a313t-86087eacc2f9c0109c88ca339b7b9841fff19e6396d806d16f33cec43bb222af3
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container_title Organic letters
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creator López-Alberca, María P
Mancheño, María J
Fernández, Israel
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Sierra, Miguel A
description The efficient copper oxidative homocoupling (CuCl/TMEDA/O2) of alkynyl Fischer carbene complexes yields bis-carbene complexes having π-tethers. The bimetallic complexes are exceptional templates to prepare diverse organic symmetric structures connected by π-extended fragments.
doi_str_mv 10.1021/ol702464r
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title Cu-Catalyzed Synthesis of Symmetric Group 6 (Fischer) Bis-carbene Complexes
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