A Thermal Spin Transition in a Nanoporous Iron(II) Coordination Framework Material

Influential guests: An abrupt spin‐crossover transition is exhibited by a nanoporous framework material that consists of interpenetrated two‐dimensional grids linked by hydrogen‐bonding interactions. Desorption of guest molecules from the highly robust host lattice occurs by a single‐crystal‐to‐sing...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2007-01, Vol.46 (12), p.2059-2062
Main Authors: Neville, Suzanne M., Moubaraki, Boujemaa, Murray, Keith S., Kepert, Cameron J.
Format: Article
Language:English
Subjects:
host-guest systems
iron
metal-organic framework
microporous materials
spin crossover
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Summary:Influential guests: An abrupt spin‐crossover transition is exhibited by a nanoporous framework material that consists of interpenetrated two‐dimensional grids linked by hydrogen‐bonding interactions. Desorption of guest molecules from the highly robust host lattice occurs by a single‐crystal‐to‐single‐crystal transformation and leads to subtle changes in the framework structure and spin‐crossover properties.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200603977