Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols

Simple chlorodiisopropylphosphine adducts of rhodium, either pre-formed or formed in situ, prove to be highly effective catalysts for the ortho-arylation of phenols.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2008-01 (8), p.990-992
Main Authors: Bedford, Robin B, Betham, Michael, Caffyn, Andrew J M, Charmant, Jonathan P H, Lewis-Alleyne, Lesley C, Long, Philip D, Polo-Cerón, Dorian, Prashar, Sanjiv
Format: Article
Language:English
Subjects:
Catalysis
Crystallography, X-Ray
Ligands
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Phenols - chemical synthesis
Phenols - chemistry
Phosphines - chemistry
Propane - analogs & derivatives
Propane - chemistry
Rhodium - chemistry
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Description
Summary:Simple chlorodiisopropylphosphine adducts of rhodium, either pre-formed or formed in situ, prove to be highly effective catalysts for the ortho-arylation of phenols.
ISSN:1359-7345
1364-548X
DOI:10.1039/b718128k