Mu2-acetato-kappa(2)O:O'-tris(mu2-ferrocenecarboxylato-kappa(2)O:O')bis[(N,N-dimethylformamide-kappaO)copper(II)]

The title compound, [Cu(2)Fe(3)(C(5)H(5))(3)(C(2)H(3)O(2))(C(6)H(4)O(2))(3)(C(3)H(7)NO)(2)], belongs to the classic dimeric paddle-wheel structure type. It is an unusual example in that it contains two different carboxylate groups, viz. ferrocenecarboxylate and acetate. With three ferrocenecarboxyla...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2008-03, Vol.64 (Pt 3), p.m121-m122
Main Authors: Luo, Jian-Hai, Huang, Chang-Cang, Huang, Xi-He, Wang, Jin-Gen
Format: Article
Language:English
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Summary:The title compound, [Cu(2)Fe(3)(C(5)H(5))(3)(C(2)H(3)O(2))(C(6)H(4)O(2))(3)(C(3)H(7)NO)(2)], belongs to the classic dimeric paddle-wheel structure type. It is an unusual example in that it contains two different carboxylate groups, viz. ferrocenecarboxylate and acetate. With three ferrocenecarboxylate groups and only one acetate group bridging the two Cu centres, a noncentrosymmetric molecular arrangement results.
ISSN:1600-5759
DOI:10.1107/S0108270107044952