Divergent Pathways in the Reaction of Fischer Carbenes and Palladium

The Pd-catalyzed reaction of β-arylaminochromium(0) carbene complexes produces by transmetalation the first isolated and X-ray structurally characterized bis-Pd(II) carbene complex, as well as other alternative reaction pathways, such as the oxidative addition−transmetalation sequence, not seen befo...

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Bibliographic Details
Published in:Organic letters 2007-04, Vol.9 (9), p.1757-1759
Main Authors: López-Alberca, María P, Mancheño, María J, Fernández, Israel, Gómez-Gallego, Mar, Sierra, Miguel A, Torres, Rosario
Format: Article
Language:English
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Summary:The Pd-catalyzed reaction of β-arylaminochromium(0) carbene complexes produces by transmetalation the first isolated and X-ray structurally characterized bis-Pd(II) carbene complex, as well as other alternative reaction pathways, such as the oxidative addition−transmetalation sequence, not seen before in this chemistry.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol070431n