Azide-Modified Graphitic Surfaces for Covalent Attachment of Alkyne-Terminated Molecules by “Click” Chemistry

Azide-modified graphitic surfaces were prepared by reaction with iodine azide. The surface-attached azides undergo the “click” reaction with alkyne-terminated molecules ethynylferrocene and 1-ethynyl-4-(trifluoromethyl)benzene. Voltammetric and XPS analyses show the surface coverage of both the azid...

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Published in:Journal of the American Chemical Society 2007-05, Vol.129 (17), p.5370-5371
Main Authors: Devadoss, Anando, Chidsey, Christopher E. D
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Language:English
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container_title Journal of the American Chemical Society
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creator Devadoss, Anando
Chidsey, Christopher E. D
description Azide-modified graphitic surfaces were prepared by reaction with iodine azide. The surface-attached azides undergo the “click” reaction with alkyne-terminated molecules ethynylferrocene and 1-ethynyl-4-(trifluoromethyl)benzene. Voltammetric and XPS analyses show the surface coverage of both the azide and the subsequent triazole of 2 × 1013 molecules/cm2. The 1,2,3-triazole linker is stable in an aqueous 1 M HCl solution for at least 60 min at 55 °C.
doi_str_mv 10.1021/ja071291f
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title Azide-Modified Graphitic Surfaces for Covalent Attachment of Alkyne-Terminated Molecules by “Click” Chemistry
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