Novel low density granular adsorbents – Properties of a composite matrix from zeolitisation of vermiculite

• Published in: Chemosphere (Oxford) 2007-06, Vol.68 (6), p.1153-1162
• Main Authors: Johnson, Christopher D., Worrall, Fred
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Aluminum Silicates - chemistry; Applied sciences; Bouyant; Chemistry; Exact sciences and technology; General and physical chemistry; Global environmental pollution; Hydro-sodalite; Ion Exchange; Low density; Materials Testing; Pollution; Surface physical chemistry; Vermiculite; Zeolite; Zeolites - chemistry
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2007.01.049

This paper reports the preparation and properties of a new low density granular absorbent material based on a zeolite/vermiculite composite. The composite prepared addresses a number of important issues relating to the use of zeolites in environmental and waste management applications. The material prepared has large particle size due to binderless adhesion of zeolite crystals within the protective lamellar matrix provided by the vermiculite granule. Additionally, the porous nature of new material ensures that it outperforms natural zeolite grains in ion-exchange tests. The material was shown to have a low bulk density (0.75 g cm −3) adding the benefit that the majority of grains float on water for over 15 h. The conclusion of the study is that the use of composite matrices enable the preparation of materials which show the physical properties of the host, (e.g., granular and low density), whilst maintaining the powder-like properties (e.g., high ion-exchange and small crystal size) of the active component. The resulting material can be easily handled and separated from aqueous waste streams using either flotation or exploiting its granular nature.