1,5-Anhydro- d-fructose from d-fructose

1,5-Anhydro- d-fructose was efficiently prepared from d-fructose via regiospecific 1,5-anhydro ring formation of 2,3- O-isopropylidene-1- O-methyl(tolyl)sulfonyl- d-fructopyranose and subsequent deprotection.

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Bibliographic Details
Published in:Carbohydrate research 2007-07, Vol.342 (9), p.1249-1253
Main Authors: Dekany, Gyula, Lundt, Inge, Niedermair, Fabian, Bichler, Sabine, Spreitz, Josef, (Fitz) Sprenger, Friedrich K., Stütz, Arnold E.
Format: Article
Language:English
Subjects:
1,5-Anhydro- d-fructose
Carbohydrate Conformation
Fructose - analogs & derivatives
Fructose - chemical synthesis
Fructose - chemistry
Models, Chemical
Molecular Structure
Synthesis
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Description
Summary:1,5-Anhydro- d-fructose was efficiently prepared from d-fructose via regiospecific 1,5-anhydro ring formation of 2,3- O-isopropylidene-1- O-methyl(tolyl)sulfonyl- d-fructopyranose and subsequent deprotection.
ISSN:0008-6215
1873-426X
DOI:10.1016/j.carres.2007.02.026