Investigation of Sulfur Extrusion from a Cyclic Dialkoxy Disulfide

The relationship of cyclic dialkoxy disulfide 11, its thionosulfite isomer 12, and the related sulfoxylate 13 has been examined. Investigations demonstrate an interconversion between thionosulfite 12 and sulfoxylate 13. This sequential transformation brings evidence that a branched-bond sulfur struc...

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Bibliographic Details
Published in:Journal of organic chemistry 2007-05, Vol.72 (10), p.3906-3908
Main Authors: Eghbali, Nicolas, Harpp, David N
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Organic chemistry
Preparations and properties
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Summary:The relationship of cyclic dialkoxy disulfide 11, its thionosulfite isomer 12, and the related sulfoxylate 13 has been examined. Investigations demonstrate an interconversion between thionosulfite 12 and sulfoxylate 13. This sequential transformation brings evidence that a branched-bond sulfur structure is likely involved in sulfur extrusion.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo062190n