Rapid gas chromatographic method for the determination of famoxadone, trifloxystrobin and fenhexamid residues in tomato, grape and wine samples

Trifloxystrobin, fenhexamid and famoxadone belong to the generation of fungicides acting against a broad spectrum of fungi and widely used in Integrated Pest Management strategies in different agricultural crops but mainly in viticulture. In the present work, a gas chromatographic (GC) method for th...

Full description

Saved in:
Bibliographic Details
Published in:Journal of Chromatography A 2007-05, Vol.1150 (1), p.208-214
Main Authors: Likas, D.T., Tsiropoulos, N.G., Miliadis, G.E.
Format: Article
Language:English
Subjects:
Acetates - analysis
Acetates - chemistry
Amides - analysis
Amides - chemistry
Biological and medical sciences
Chromatography, Gas - methods
famoxadone
Famoxadone residues
Fenhexamid
Fermented food industries
Food analysis
food contamination
Food industries
Fruit and vegetable industries
Fundamental and applied biological sciences. Psychology
fungicide residues
fungicides
Gas chromatography
grapes
Imines - analysis
Imines - chemistry
Lycopersicon esculentum - chemistry
Methacrylates - analysis
Methacrylates - chemistry
Method comparison
Oxazoles - analysis
Oxazoles - chemistry
Plant Extracts - analysis
Plant Extracts - chemistry
rapid methods
Reproducibility of Results
Strobilurins
tomatoes
Trifloxystrobin
Uncertainty
Vitis - chemistry
Wine - analysis
wines
Wines and vinegars
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Trifloxystrobin, fenhexamid and famoxadone belong to the generation of fungicides acting against a broad spectrum of fungi and widely used in Integrated Pest Management strategies in different agricultural crops but mainly in viticulture. In the present work, a gas chromatographic (GC) method for their determination was developed and validated on tomato, grape and wine matrices. The method was based on a simple one step liquid–liquid microextraction with cyclohexane/dichloromethane (9 + 1, v/v) and determination of fungicides by gas chromatography with nitrogen phosphorous (NP-) and electron capture (EC-) detection, and ion trap mass spectrometry (ITMS) for confirmation. The method was validated by recovery experiments, assessment of matrix effect and calculation of the associated uncertainty. Recoveries for GC-NPD and GC-ECD were found in the range of 81–102% with RSD
ISSN:0021-9673
DOI:10.1016/j.chroma.2006.08.041