Gold(I)-Catalyzed Rearrangement of Alkynyloxiranes:  A Mild Access to Divinyl Ketones

Acyloxylated divinyl ketones are conveniently formed by a new gold(I)-catalyzed rearrangement of (3-acyloxyprop-1-ynyl)oxiranes.

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Bibliographic Details
Published in:Organic letters 2008-04, Vol.10 (8), p.1569-1572
Main Authors: Cordonnier, Marie-Caroline, Blanc, Aurélien, Pale, Patrick
Format: Article
Language:English
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Summary:Acyloxylated divinyl ketones are conveniently formed by a new gold(I)-catalyzed rearrangement of (3-acyloxyprop-1-ynyl)oxiranes.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol800219k