Lead Hydro Sodalite [Pb2(OH)(H2O)3]2[Al3Si3O12]2: Synthesis and Structure Determination by Combining X-ray Rietveld Refinement, 1H MAS NMR FTIR and XANES Spectroscopy

The same novel, orientationally disordered lead complex, [Pb2(OH)(H2O)3]2[Al3Si3O12]2, was obtained by ion exchange of various sodium hydro sodalites with aqueous Pb(NO3)2 solutions, whichever sodalite reactant was used. A model of the structure was developed, as illustrated.

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Published in:Chemistry : a European journal 2000-01, Vol.6 (2), p.292-297
Main Authors: Eiden-Aßmann, Stefanie, Schneider, A. M., Behrens, Peter, Wiebcke, Michael, Engelhardt, Günter, Felsche, Jürgen
Format: Article
Language:English
Subjects:
Host-guest chemistry
Ion exchange
Lead
Sodalites
Structure elucidation
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container_issue 2
container_start_page 292
container_title Chemistry : a European journal
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creator Eiden-Aßmann, Stefanie
Schneider, A. M.
Behrens, Peter
Wiebcke, Michael
Engelhardt, Günter
Felsche, Jürgen
description The same novel, orientationally disordered lead complex, [Pb2(OH)(H2O)3]2[Al3Si3O12]2, was obtained by ion exchange of various sodium hydro sodalites with aqueous Pb(NO3)2 solutions, whichever sodalite reactant was used. A model of the structure was developed, as illustrated.
doi_str_mv 10.1002/(SICI)1521-3765(20000117)6:2<292::AID-CHEM292>3.0.CO;2-M
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source Wiley-Blackwell Read & Publish Collection
subjects Host-guest chemistry
Ion exchange
Lead
Sodalites
Structure elucidation
title Lead Hydro Sodalite [Pb2(OH)(H2O)3]2[Al3Si3O12]2: Synthesis and Structure Determination by Combining X-ray Rietveld Refinement, 1H MAS NMR FTIR and XANES Spectroscopy
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