The first bona-fide sodium complex of hydrotris(methimazolyl)borate: an example of sodium exhibiting a preference for sulfur over oxygen

The synthesis and structure of two related sodium complexes are reported which demonstrate that sulfur can preferentially complex to sodium irrespective of the presence of more apposite donor species such as DMF.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2007-01 (22), p.2242-2244
Main Authors: Biernat, Anne, Schwalbe, Matthias, Wallace, Dawn, Reglinski, John, Spicer, Mark D
Format: Article
Language:English
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Summary:The synthesis and structure of two related sodium complexes are reported which demonstrate that sulfur can preferentially complex to sodium irrespective of the presence of more apposite donor species such as DMF.
ISSN:1477-9226
1477-9234
DOI:10.1039/b705161c