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The Influence of the Molecular Dipole on the Electronic Structure of Isomeric Icosahedral Dicarbadodecaborane and Phosphacarbadodecaborane Molecular Films
We compare the molecular films of three different isomers of closo-dicarbadodecaborane (orthocarborane (1,2-C2B10H12), metacarborane (1,7-C2B10H12), paracarborane (1,12-C2B10H12)) and two related icosahedral cage molecules, 1-phospha-2-carbadodecaborane (1,2-PCB10H11) and 1-phospha-7-carbadodecabora...
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| Published in: | The journal of physical chemistry. B 2007-06, Vol.111 (25), p.7009-7016 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-a417t-1df78f352e06740ee3f048643fd0bc4c526a74476ddf66a5c7003a4b87dd4913 |
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| cites | cdi_FETCH-LOGICAL-a417t-1df78f352e06740ee3f048643fd0bc4c526a74476ddf66a5c7003a4b87dd4913 |
| container_end_page | 7016 |
| container_issue | 25 |
| container_start_page | 7009 |
| container_title | The journal of physical chemistry. B |
| container_volume | 111 |
| creator | Balaz, Snjezana Caruso, A. N Platt, N. P Dimov, D. I Boag, N. M Brand, J. I Losovyj, Ya. B Dowben, P. A |
| description | We compare the molecular films of three different isomers of closo-dicarbadodecaborane (orthocarborane (1,2-C2B10H12), metacarborane (1,7-C2B10H12), paracarborane (1,12-C2B10H12)) and two related icosahedral cage molecules, 1-phospha-2-carbadodecaborane (1,2-PCB10H11) and 1-phospha-7-carbadodecaborane (1,7-PCB10H11) adsorbed on a variety of substrates. While the experimental electronic structure from combined photoemission and inverse photoemission studies of the molecular films are in good agreement with semiempirical calculations for the isolated molecule, there is a shift in the chemical potential for each molecule. The experimental position of the molecular chemical potential implicates an influence of both interface and adsorbate dipole. |
| doi_str_mv | 10.1021/jp0703760 |
| format | article |
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| ispartof | The journal of physical chemistry. B, 2007-06, Vol.111 (25), p.7009-7016 |
| issn | 1520-6106 1520-5207 |
| language | eng |
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| source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
| title | The Influence of the Molecular Dipole on the Electronic Structure of Isomeric Icosahedral Dicarbadodecaborane and Phosphacarbadodecaborane Molecular Films |
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