Second-Order Jahn-Teller Effect in a Host-Guest Complex

A quick in and out: A supramolecular cluster encapsulates a cation guest with a linear alkyl side chain, which rapidly extends and retracts through apertures in the triangular faces of the tetrahedral host. This motion results in a dynamic second‐order Jahn–Teller distortion (see picture).

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Published in:Angewandte Chemie International Edition 2007-01, Vol.46 (26), p.4976-4978
Main Authors: Tiedemann, Bryan E. F., Raymond, Kenneth N.
Format: Article
Language:English
Subjects:
fluxionality
host-guest systems
Jahn-Teller distortion
supramolecular chemistry
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cited_by cdi_FETCH-LOGICAL-c4072-dbaa38e450f9a267bba32969e4699c5e6e77b1d3b87c3b85ae556831cc4405ff3
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description A quick in and out: A supramolecular cluster encapsulates a cation guest with a linear alkyl side chain, which rapidly extends and retracts through apertures in the triangular faces of the tetrahedral host. This motion results in a dynamic second‐order Jahn–Teller distortion (see picture).
doi_str_mv 10.1002/anie.200701002
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source Wiley-Blackwell Read & Publish Collection
subjects fluxionality
host-guest systems
Jahn-Teller distortion
supramolecular chemistry
title Second-Order Jahn-Teller Effect in a Host-Guest Complex
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