The Geometric and Electronic Structure of a One-Electron-Oxidized Nickel(II) Bis(salicylidene)diamine Complex

Class III delocalization? The isolation and analysis of the ligand‐radical title complex has allowed description of the changes in bonding from the reduced form as well as the extent of delocalization. The intense low‐energy absorption of the oxidized complex can be described as a ligand‐radical tra...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2007-01, Vol.46 (27), p.5198-5201
Main Authors: Storr, Tim, Wasinger, Erik C., Pratt, Russell C., Stack, T. Daniel P.
Format: Article
Language:English
Subjects:
Electron Spin Resonance Spectroscopy
electronic structure
Electrons
mixed-valent compounds
Models, Molecular
Molecular Structure
N,O ligands
nickel
O ligands
Organometallic Compounds - chemistry
oxidation
Oxidation-Reduction
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Summary:Class III delocalization? The isolation and analysis of the ligand‐radical title complex has allowed description of the changes in bonding from the reduced form as well as the extent of delocalization. The intense low‐energy absorption of the oxidized complex can be described as a ligand‐radical transition of a highly delocalized class III mixed‐valence compound.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200701194