Silver-Catalyzed Intermolecular Amination of CH Groups

Teamwork: The dinuclear silver complex [Ag2(OTf)2(bp)2] (OTf=trifluoromethanesulfonate, bp=bathophenanthroline) catalyzes the intermolecular amination of saturated CH bonds by using PhINNs (Ns=p‐nitrosulfonyl) as the nitrene precursor (see scheme). Preliminary investigations suggest that the dinuc...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2007-01, Vol.46 (27), p.5184-5186
Main Authors: Li, Zigang, Capretto, D. A., Rahaman, R., He, Chuan
Format: Article
Language:English
Subjects:
Amination
Carbon - chemistry
Catalysis
Crystallography, X-Ray
CH activation
homogeneous catalysis
Hydrogen - chemistry
Ligands
Models, Molecular
Molecular Structure
nitrene transfer
silver
Silver - chemistry
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Summary:Teamwork: The dinuclear silver complex [Ag2(OTf)2(bp)2] (OTf=trifluoromethanesulfonate, bp=bathophenanthroline) catalyzes the intermolecular amination of saturated CH bonds by using PhINNs (Ns=p‐nitrosulfonyl) as the nitrene precursor (see scheme). Preliminary investigations suggest that the dinuclear structural motif is crucial to catalytic performance.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200700760