Synthesis, structure and properties of 1,19-disubstituted tetradehydrocorrin cobalt complexes

1,19-Disubstituted tetradehydrocorrins have a ring structure that is closely related to the corrin ring found in vitamin B 12. We herein report the isolation and full characterization of a Co(I)-TDHC species and X-ray crystal structures and full characterization of related Co(II) and Co(III) corrins...

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Published in:Journal of inorganic biochemistry 2001-01, Vol.83 (2), p.133-138
Main Authors: Liu, Chun-Jing, Thompson, Alison, Dolphin, David
Format: Article
Language:English
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Co(I)/Co(II)/Co(III)–tetradehydrocorrins
Tetradehydrocorrin
Vitamin B 12 model
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container_title Journal of inorganic biochemistry
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description 1,19-Disubstituted tetradehydrocorrins have a ring structure that is closely related to the corrin ring found in vitamin B 12. We herein report the isolation and full characterization of a Co(I)-TDHC species and X-ray crystal structures and full characterization of related Co(II) and Co(III) corrins as models for vitamin B 12 complexes.
doi_str_mv 10.1016/S0162-0134(00)00178-1
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subjects Co(I)/Co(II)/Co(III)–tetradehydrocorrins
Tetradehydrocorrin
Vitamin B 12 model
title Synthesis, structure and properties of 1,19-disubstituted tetradehydrocorrin cobalt complexes
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