Selective modification of beta-cyclodextrin: an unexpected tandem reaction enables the cross-linking of C2(A) and C2(B) via a sulfur atom

2(A),3(A)-Alloepithio-2(B)-sulfonyl-beta-cyclodextrin undergoes a tandem reaction to generate an unprecedented C2(A)-S-C2(B)-bridged glucosyl-3(A),6(A)-anhydroglucoside segment.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2007-08 (30), p.3157-3159
Main Authors: Fukudome, Makoto, Yoshikawa, Kazuki, Koga, Kazutaka, Yuan, De-Qi, Fujita, Kahee
Format: Article
Language:English
Subjects:
beta-Cyclodextrins - chemistry
Glucosides - chemistry
Nuclear Magnetic Resonance, Biomolecular
Online Access:Get full text
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Description
Summary:2(A),3(A)-Alloepithio-2(B)-sulfonyl-beta-cyclodextrin undergoes a tandem reaction to generate an unprecedented C2(A)-S-C2(B)-bridged glucosyl-3(A),6(A)-anhydroglucoside segment.
ISSN:1359-7345
DOI:10.1039/b703943c