How are tris(triazolyl)borate ligands electronically different from tris(pyrazolyl)borate ligands? A study of (Ttz(tBu,Me))CuCO [Ttz(tBu,Me) = tris(3-t-butyl-5-methyl-1,2,4-triazolyl)borate]

(Ttz(tBu,Me))CuCO [Ttz(tBu,Me) = tris(3-t-butyl-5-methyl-1,2,4-triazolyl)borate] was prepared and fully characterized to test whether the Ttz(tBu,Me) ligand, which is sterically similar to Tp(tBu,Me) is electronically different; Ttz(tBu,Me) is a weaker electron donor and (Ttz(tBu,Me))CuCO is water s...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2008-01 (22), p.2923-2925
Main Authors: Papish, Elizabeth T, Donahue, Trisha M, Wells, Kirsten R, Yap, Glenn P A
Format: Article
Language:English
Subjects:
Borates - chemistry
Carbon Monoxide - chemistry
Copper - chemistry
Crystallography, X-Ray
Electrons
Ligands
Models, Molecular
Molecular Structure
Organometallic Compounds - chemistry
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Summary:(Ttz(tBu,Me))CuCO [Ttz(tBu,Me) = tris(3-t-butyl-5-methyl-1,2,4-triazolyl)borate] was prepared and fully characterized to test whether the Ttz(tBu,Me) ligand, which is sterically similar to Tp(tBu,Me) is electronically different; Ttz(tBu,Me) is a weaker electron donor and (Ttz(tBu,Me))CuCO is water stable and has a propensity to form hydrogen bonds.
ISSN:1477-9226
1477-9234
DOI:10.1039/b804951c