A General High-Yield Route to Bis(salicylaldimine) Zinc(II) Complexes:  Application to the Synthesis of Pyridine-Modified Salen-Type Zinc(II) Complexes

A general, direct, and high-yield synthesis of bis(salicylaldimine) zinc complexes from the ligands and Et2Zn is reported. This synthetic method is particularly valuable, not only because it allows the efficient preparation of salen-type complexes of zinc but also because it can be used to prepare b...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry 2001-06, Vol.40 (13), p.3222-3227
Main Authors: Morris, Gregory A, Zhou, Hongying, Stern, Charlotte L, Nguyen, SonBinh T
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a415t-c1bfa566b14de4abd4d731c5f9c90b920718b0c58bc16c06db16c728366ef233
cites cdi_FETCH-LOGICAL-a415t-c1bfa566b14de4abd4d731c5f9c90b920718b0c58bc16c06db16c728366ef233
container_end_page 3227
container_issue 13
container_start_page 3222
container_title Inorganic chemistry
container_volume 40
creator Morris, Gregory A
Zhou, Hongying
Stern, Charlotte L
Nguyen, SonBinh T
description A general, direct, and high-yield synthesis of bis(salicylaldimine) zinc complexes from the ligands and Et2Zn is reported. This synthetic method is particularly valuable, not only because it allows the efficient preparation of salen-type complexes of zinc but also because it can be used to prepare bifunctional pyridine-modified zinc(II) bis(salicylidene) complexes, which are potentially useful compounds for applications in asymmetric catalysis and materials chemistry. The synthesis and complete structural characterization of a new series of pyridine-modified zinc(II) bis(salicylidene) ligands is discussed.
doi_str_mv 10.1021/ic010090o
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_70908153</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>70908153</sourcerecordid><originalsourceid>FETCH-LOGICAL-a415t-c1bfa566b14de4abd4d731c5f9c90b920718b0c58bc16c06db16c728366ef233</originalsourceid><addsrcrecordid>eNpt0c1u1DAUBWALgejQsuAFkDegziLUNz_OhN10RNtRW1GYkYBuLMe-oW6dOMSJ1OzY8gi8Hk-CRzNqN11dS_58LJ1LyBtgH4DFcGQUA8YK5p6RCWQxizJg35-TCWPhDJwXe-SV97csmCTlL8keQFIUUPAJ-Tunp9hgJy09Mz9voh8GraZf3dAj7R09Nv7QS2vUaKXVpjYNTum1adThcjmlC1e3Fu_Rf_z3-w-dt22Asjeu2Tztb5CuxiYMbzx1Fb0aO6NDQHTptKkMarqSFptoPbb4ROYBeVFJ6_H1bu6T9cmn9eIsuvh8ulzMLyKZQtZHCspKZpyXkGpMZalTnSegsqpQBSuLmOUwK5nKZqUCrhjXZRh5PEs4xypOkn3yfhvbdu7XgL4XtfEKrZUNusGLPPQ6g2wDp1uoOud9h5VoO1PLbhTAxGYN4mENwb7dhQ5ljfpR7noPINoC43u8f7iX3Z3geZJnYn21EtfHX06-na8ScR78u62XyotbN3RNqOSJj_8D7ZSfOg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>70908153</pqid></control><display><type>article</type><title>A General High-Yield Route to Bis(salicylaldimine) Zinc(II) Complexes:  Application to the Synthesis of Pyridine-Modified Salen-Type Zinc(II) Complexes</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Morris, Gregory A ; Zhou, Hongying ; Stern, Charlotte L ; Nguyen, SonBinh T</creator><creatorcontrib>Morris, Gregory A ; Zhou, Hongying ; Stern, Charlotte L ; Nguyen, SonBinh T</creatorcontrib><description>A general, direct, and high-yield synthesis of bis(salicylaldimine) zinc complexes from the ligands and Et2Zn is reported. This synthetic method is particularly valuable, not only because it allows the efficient preparation of salen-type complexes of zinc but also because it can be used to prepare bifunctional pyridine-modified zinc(II) bis(salicylidene) complexes, which are potentially useful compounds for applications in asymmetric catalysis and materials chemistry. The synthesis and complete structural characterization of a new series of pyridine-modified zinc(II) bis(salicylidene) ligands is discussed.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic010090o</identifier><identifier>PMID: 11399196</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Inorganic chemistry, 2001-06, Vol.40 (13), p.3222-3227</ispartof><rights>Copyright © 2001 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a415t-c1bfa566b14de4abd4d731c5f9c90b920718b0c58bc16c06db16c728366ef233</citedby><cites>FETCH-LOGICAL-a415t-c1bfa566b14de4abd4d731c5f9c90b920718b0c58bc16c06db16c728366ef233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11399196$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Morris, Gregory A</creatorcontrib><creatorcontrib>Zhou, Hongying</creatorcontrib><creatorcontrib>Stern, Charlotte L</creatorcontrib><creatorcontrib>Nguyen, SonBinh T</creatorcontrib><title>A General High-Yield Route to Bis(salicylaldimine) Zinc(II) Complexes:  Application to the Synthesis of Pyridine-Modified Salen-Type Zinc(II) Complexes</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>A general, direct, and high-yield synthesis of bis(salicylaldimine) zinc complexes from the ligands and Et2Zn is reported. This synthetic method is particularly valuable, not only because it allows the efficient preparation of salen-type complexes of zinc but also because it can be used to prepare bifunctional pyridine-modified zinc(II) bis(salicylidene) complexes, which are potentially useful compounds for applications in asymmetric catalysis and materials chemistry. The synthesis and complete structural characterization of a new series of pyridine-modified zinc(II) bis(salicylidene) ligands is discussed.</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNpt0c1u1DAUBWALgejQsuAFkDegziLUNz_OhN10RNtRW1GYkYBuLMe-oW6dOMSJ1OzY8gi8Hk-CRzNqN11dS_58LJ1LyBtgH4DFcGQUA8YK5p6RCWQxizJg35-TCWPhDJwXe-SV97csmCTlL8keQFIUUPAJ-Tunp9hgJy09Mz9voh8GraZf3dAj7R09Nv7QS2vUaKXVpjYNTum1adThcjmlC1e3Fu_Rf_z3-w-dt22Asjeu2Tztb5CuxiYMbzx1Fb0aO6NDQHTptKkMarqSFptoPbb4ROYBeVFJ6_H1bu6T9cmn9eIsuvh8ulzMLyKZQtZHCspKZpyXkGpMZalTnSegsqpQBSuLmOUwK5nKZqUCrhjXZRh5PEs4xypOkn3yfhvbdu7XgL4XtfEKrZUNusGLPPQ6g2wDp1uoOud9h5VoO1PLbhTAxGYN4mENwb7dhQ5ljfpR7noPINoC43u8f7iX3Z3geZJnYn21EtfHX06-na8ScR78u62XyotbN3RNqOSJj_8D7ZSfOg</recordid><startdate>20010618</startdate><enddate>20010618</enddate><creator>Morris, Gregory A</creator><creator>Zhou, Hongying</creator><creator>Stern, Charlotte L</creator><creator>Nguyen, SonBinh T</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20010618</creationdate><title>A General High-Yield Route to Bis(salicylaldimine) Zinc(II) Complexes:  Application to the Synthesis of Pyridine-Modified Salen-Type Zinc(II) Complexes</title><author>Morris, Gregory A ; Zhou, Hongying ; Stern, Charlotte L ; Nguyen, SonBinh T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a415t-c1bfa566b14de4abd4d731c5f9c90b920718b0c58bc16c06db16c728366ef233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Morris, Gregory A</creatorcontrib><creatorcontrib>Zhou, Hongying</creatorcontrib><creatorcontrib>Stern, Charlotte L</creatorcontrib><creatorcontrib>Nguyen, SonBinh T</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Morris, Gregory A</au><au>Zhou, Hongying</au><au>Stern, Charlotte L</au><au>Nguyen, SonBinh T</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A General High-Yield Route to Bis(salicylaldimine) Zinc(II) Complexes:  Application to the Synthesis of Pyridine-Modified Salen-Type Zinc(II) Complexes</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2001-06-18</date><risdate>2001</risdate><volume>40</volume><issue>13</issue><spage>3222</spage><epage>3227</epage><pages>3222-3227</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>A general, direct, and high-yield synthesis of bis(salicylaldimine) zinc complexes from the ligands and Et2Zn is reported. This synthetic method is particularly valuable, not only because it allows the efficient preparation of salen-type complexes of zinc but also because it can be used to prepare bifunctional pyridine-modified zinc(II) bis(salicylidene) complexes, which are potentially useful compounds for applications in asymmetric catalysis and materials chemistry. The synthesis and complete structural characterization of a new series of pyridine-modified zinc(II) bis(salicylidene) ligands is discussed.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>11399196</pmid><doi>10.1021/ic010090o</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0020-1669
ispartof Inorganic chemistry, 2001-06, Vol.40 (13), p.3222-3227
issn 0020-1669
1520-510X
language eng
recordid cdi_proquest_miscellaneous_70908153
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
title A General High-Yield Route to Bis(salicylaldimine) Zinc(II) Complexes:  Application to the Synthesis of Pyridine-Modified Salen-Type Zinc(II) Complexes
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T07%3A54%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20General%20High-Yield%20Route%20to%20Bis(salicylaldimine)%20Zinc(II)%20Complexes:%E2%80%89%20Application%20to%20the%20Synthesis%20of%20Pyridine-Modified%20Salen-Type%20Zinc(II)%20Complexes&rft.jtitle=Inorganic%20chemistry&rft.au=Morris,%20Gregory%20A&rft.date=2001-06-18&rft.volume=40&rft.issue=13&rft.spage=3222&rft.epage=3227&rft.pages=3222-3227&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/ic010090o&rft_dat=%3Cproquest_cross%3E70908153%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a415t-c1bfa566b14de4abd4d731c5f9c90b920718b0c58bc16c06db16c728366ef233%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=70908153&rft_id=info:pmid/11399196&rfr_iscdi=true