Amidate complexes of titanium and zirconium: a new class of tunable precatalysts for the hydroamination of alkynes

A series of bis(amidate)group 4-bis(amido) complexes have been prepared, characterized and have been shown to be highly tunable precatalysts for both the intra- and intermolecular hydroamination of alkynes.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2003-10 (19), p.2462-2463
Main Authors: Li, Chunyu, Thomson, Robert K, Gillon, Bronwyn, Patrick, Brian O, Schafer, Laurel L
Format: Article
Language:English
Online Access:Get full text
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Description
Summary:A series of bis(amidate)group 4-bis(amido) complexes have been prepared, characterized and have been shown to be highly tunable precatalysts for both the intra- and intermolecular hydroamination of alkynes.
ISSN:1359-7345
DOI:10.1039/b304176j