A cascade of reactions involving anchimeric assistance leads to a highly 'crowded' hexa(alkylcarboxy)benzene

The substitution of hexabromomethylbenzene with 1-adamantyl carboxylate quantitatively leads to the corresponding hexacyl derivative via anchimeric assistance by the alkylcarboxy substituents.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2001-12 (23), p.2436-2437
Main Authors: Hennrich, G, Lynch, V M, Anslyn, E V
Format: Article
Language:English
Online Access:Get full text
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Summary:The substitution of hexabromomethylbenzene with 1-adamantyl carboxylate quantitatively leads to the corresponding hexacyl derivative via anchimeric assistance by the alkylcarboxy substituents.
ISSN:1359-7345
DOI:10.1039/b105569k