Successive intramolecular transiminations in an iron (II) complex with chiral tridentate ligands

Two molecules of S-2-pyridylmethylidene-1-(2-pyridyl)ethylamine coordinated to an iron(II) undergo successive transiminations yielding bis[1-(2-pyridyl)ethylidene-2-pyridylmethylamine]iron(II) in acetonitrile.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2001-11 (22), p.2388-2389
Main Authors: Chavez-Gil, T E, Yasaka, M, Senokuchi, T, Sumimoto, M, Kurosaki, H, Goto, M
Format: Article
Language:English
Subjects:
Imines - chemistry
Iron Compounds - chemistry
Kinetics
Ligands
Magnetic Resonance Spectroscopy
Stereoisomerism
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Description
Summary:Two molecules of S-2-pyridylmethylidene-1-(2-pyridyl)ethylamine coordinated to an iron(II) undergo successive transiminations yielding bis[1-(2-pyridyl)ethylidene-2-pyridylmethylamine]iron(II) in acetonitrile.
ISSN:1359-7345
1364-548X
DOI:10.1039/b107502k