Additional of functional vinylzinc reagents to nitrones: synthesis of (E)-N-allylhydroxylamines and their rearrangement into (E)-O-allylhydroxylamines

The vinylzinc reagents derived from hydrozirconation of alkynes and transmetallation add readily to nitrones to yield pure (E)-N-allylhydroxylamines; some of these rearrange into O-allylhydroxylamines.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2001-09 (18), p.1806-1807
Main Authors: Pandya, S U, Garçon, C, Chavant, P Y, Py, S, Vallée, Y
Format: Article
Language:English
Online Access:Get full text
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Description
Summary:The vinylzinc reagents derived from hydrozirconation of alkynes and transmetallation add readily to nitrones to yield pure (E)-N-allylhydroxylamines; some of these rearrange into O-allylhydroxylamines.
ISSN:1359-7345