Ni(III) Complex of an N-Confused Porphyrin Inner C-Oxide

A novel, structurally characterized Ni(III) complex of an N-confused porphyrin inner C-oxide has been synthesized from the oxidation of a Ni(II) N-confused porphyrin using OsO4. Crystal data:  C53H40N5NiO·CH2Cl2, monoclinic, space group P2/a (No. 13), a = 21.229(1) Å, b = 8.6451(5) Å, c = 25.762(2)...

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Bibliographic Details
Published in:Inorganic chemistry 2003-12, Vol.42 (25), p.8125-8127
Main Authors: Xiao, Ziwei, Patrick, Brian O, Dolphin, David
Format: Article
Language:English
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Summary:A novel, structurally characterized Ni(III) complex of an N-confused porphyrin inner C-oxide has been synthesized from the oxidation of a Ni(II) N-confused porphyrin using OsO4. Crystal data:  C53H40N5NiO·CH2Cl2, monoclinic, space group P2/a (No. 13), a = 21.229(1) Å, b = 8.6451(5) Å, c = 25.762(2) Å, β = 93.004(3)°, V = 4721.6(5) Å3, and Z = 4.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic020701s