A New Entry to the Isogeissoschizoid Skeleton

The tetracyclic isogeissoschizoid skeleton has been prepared by a novel route that involves the ozonolysis and double reductive amination of a cyclopentene, a nickel-catalyzed cyclization, and a late-stage Fischer indole synthesis.

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Bibliographic Details
Published in:Organic letters 2002-02, Vol.4 (4), p.615-617
Main Authors: Fornicola, Richard S, Subburaj, Kandasamy, Montgomery, John
Format: Article
Language:English
Subjects:
Amination
Carbolines - chemical synthesis
Carbolines - chemistry
Catalysis
Cyclization
Molecular Conformation
Plants - chemistry
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Description
Summary:The tetracyclic isogeissoschizoid skeleton has been prepared by a novel route that involves the ozonolysis and double reductive amination of a cyclopentene, a nickel-catalyzed cyclization, and a late-stage Fischer indole synthesis.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol017213t