Trans Doubly N-Confused Porphyrins:  Cu(III) Complexation and Formation of Rodlike Hydrogen-Bonding Networks

A trans type of doubly N-confused isomer of NCP (trans-N2CP) was synthesized via N-confused fused porphyrin (NcFP). The aromatic feature of trans-N2CP due to 18π electronic system is contrasted to the weak aromaticity of cis-derivative. The solid-state structure of trans-N2CP exhibits π-stacking col...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the American Chemical Society 2003-12, Vol.125 (51), p.15690-15691
Main Authors: Maeda, Hiromitsu, Osuka, Atsuhiro, Furuta, Hiroyuki
Format: Article
Language:English
Subjects:
Chemistry
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Preparations and properties
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A trans type of doubly N-confused isomer of NCP (trans-N2CP) was synthesized via N-confused fused porphyrin (NcFP). The aromatic feature of trans-N2CP due to 18π electronic system is contrasted to the weak aromaticity of cis-derivative. The solid-state structure of trans-N2CP exhibits π-stacking column, while the Cu(III) complex shows 1-D rodlike hydrogen bonding chain comparable with the zigzag hydrogen-bonding chain of cis-derivatives.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja038519t