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Probe beam deflection study of ion exchange in self-assembled redox polyelectrolyte thin films

Probe beam deflection during chronoamperometric oxidation-reduction of osmium complex in layer-by-layer self-assembled redox active polyelectrolyte multilayers has shown that the nature of the charge in the topmost layer determines the ion flux that balances the redox charge.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2003-12 (24), p.3014-3015
Main Authors: Grumelli, Doris E, Wolosiuk, Alejandro, Forzani, Erica, Planes, Gabriel A, Barbero, CĂ©sar, Calvo, Ernesto J
Format: Article
Language:English
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Description
Summary:Probe beam deflection during chronoamperometric oxidation-reduction of osmium complex in layer-by-layer self-assembled redox active polyelectrolyte multilayers has shown that the nature of the charge in the topmost layer determines the ion flux that balances the redox charge.
ISSN:1359-7345
1364-548X
DOI:10.1039/b308449c