Sorption equilibria of metal ions on bone char

• Published in: Chemosphere (Oxford) 2004, Vol.54 (3), p.273-281
• Main Authors: Ko, Danny C.K., Cheung, Chun Wai, Choy, Keith K.H., Porter, John F., McKay, Gordon
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Applied sciences; Bone and Bones - chemistry; Cadmium; Charcoal - chemistry; Chemistry; Copper; Exact sciences and technology; General and physical chemistry; General purification processes; Ideal adsorbed solution theory; Kinetics; Metals, Heavy - chemistry; Models, Chemical; Multicomponent equilibrium isotherm; Pollution; Surface physical chemistry; Wastewaters; Water Purification - methods; Water treatment and pollution; Zinc
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2003.08.004

The ability of bone char to adsorb three metal ions, namely, copper(II), zinc(II) and cadmium(II) ions from wastewater has been studied. Three single-component equilibrium systems and three binary equilibrium systems have been measured experimentally. The three single-component equilibrium data were analyzed using the Langmuir and the Sips equilibrium isotherm equations. The Sips isotherm gave a better fit of the experimental data than the Langmuir isotherm based on the sum of squares errors (SSE) analysis. The Cu–Zn, Cu–Cd and Cd–Zn binary equilibrium experimental data were examined by incorporating the Langmuir and the Sips isotherm equations into the ideal adsorbed solution theory (IAST). The solution methods and the predicted results for the three binary systems at different metal ion compositions have been evaluated. In addition, the application of the IAST to the model prediction for the fixed bed system is presented.