Stable P−N Bridged Cyclophosphazenes with a Spiro or Ansa Arrangement

Deprotonation reactions of cyclophosphazenes containing secondary amino groups in the side chain lead to a doubly bridged tricyclophosphazene structure or to a cyclophosphazene−cyclophosphazane−cyclophosphazene compound, which are very stable and could be used as building blocks for larger structure...

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Bibliographic Details
Published in:Inorganic chemistry 2008-06, Vol.47 (12), p.5042-5044
Main Authors: Beşli, Serap, Coles, Simon J, Davies, David B, Erkovan, Ayşen O, Hursthouse, Michael B, Kılıç, Adem
Format: Article
Language:English
Subjects:
Chain reactions
Chains
Crystallization
Crystallography, X-Ray
Magnetic Resonance Spectroscopy
Models, Molecular
Molecular Structure
Nitrogen - chemistry
Organophosphorus Compounds - chemistry
Phosphorus - chemistry
Positioning
Spiro Compounds - chemistry
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Summary:Deprotonation reactions of cyclophosphazenes containing secondary amino groups in the side chain lead to a doubly bridged tricyclophosphazene structure or to a cyclophosphazene−cyclophosphazane−cyclophosphazene compound, which are very stable and could be used as building blocks for larger structures.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic800641s