Assembling Process of Charged Nonanuclear Cationic Lanthanide(III) Clusters Assisted by Dichromium Decacarbonyl Hydride

The reaction of Ln(acac)3·3H2O (Ln = Sm, Eu, Gd, Dy, Yb) with K[Cr2(CO)10(μ-H)] at different molar ratios and solvents leads to the formation of nonanuclear lanthanide hydroxo acetylacetonate complexes of general formula [Ln9(OH)10(acac)16][HCr2(CO)10]. The compounds are isomorphous, and the common...

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Published in:Inorganic chemistry 2004-03, Vol.43 (5), p.1603-1605
Main Authors: Addamo, Maurizio, Bombieri, Gabriella, Foresti, Elisabetta, Grillone, M. Domenica, Volpe, Maurizio
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description The reaction of Ln(acac)3·3H2O (Ln = Sm, Eu, Gd, Dy, Yb) with K[Cr2(CO)10(μ-H)] at different molar ratios and solvents leads to the formation of nonanuclear lanthanide hydroxo acetylacetonate complexes of general formula [Ln9(OH)10(acac)16][HCr2(CO)10]. The compounds are isomorphous, and the common cationic cluster core consists of a novel square antiprismatic arrangement of nine Ln atoms connected by μ3, μ4 hydroxo bridges and/or by acetylacetonate ligands as it results from the single-crystal X-ray analysis of the Sm derivative for which the most suitable crystals were obtained.
doi_str_mv 10.1021/ic034700r
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title Assembling Process of Charged Nonanuclear Cationic Lanthanide(III) Clusters Assisted by Dichromium Decacarbonyl Hydride
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