Application of solid-phase microextraction to the recovery of explosives and ignitable liquid residues from forensic specimens

A current review of the application of solid-phase microextraction (SPME) to the analysis of ignitable liquids and explosive residues is presented along with experimental results demonstrating the relative effects of controllable variables. Variables discussed include fiber chemistry, adsorption and...

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Published in:Journal of Chromatography A 2000-07, Vol.885 (1), p.419-432
Main Authors: Furton, K.G., Almirall, J.R., Bi, M., Wang, J., Wu, L.
Format: Article
Language:English
Subjects:
Chemistry Techniques, Analytical
Chromatography, Gas - methods
Chromatography, High Pressure Liquid - methods
Crime
Explosions
Explosives
Ignitable liquids
Organic Chemicals - analysis
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description A current review of the application of solid-phase microextraction (SPME) to the analysis of ignitable liquids and explosive residues is presented along with experimental results demonstrating the relative effects of controllable variables. Variables discussed include fiber chemistry, adsorption and desorption temperatures, extraction and desorption times, fiber sampling placement (direct, headspace, and partial headspace) and matrix effects, including water content. SPME is shown to be an inexpensive, rapid and sensitive method for the analysis of ignitable liquids and high explosives residues from solid debris samples and from aqueous samples. Explosives are readily detected at parts per trillion concentrations and ignitable liquids are reproducibly detected at levels below those using conventional methods.
doi_str_mv 10.1016/S0021-9673(00)00368-X
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subjects Chemistry Techniques, Analytical
Chromatography, Gas - methods
Chromatography, High Pressure Liquid - methods
Crime
Explosions
Explosives
Ignitable liquids
Organic Chemicals - analysis
title Application of solid-phase microextraction to the recovery of explosives and ignitable liquid residues from forensic specimens
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